Disposal system for contaminated
hydrogen from a nuclear reactor

ABSTRACT

AN APPARATUS FOR DISPOSING OF CONTAMINATED HYDROGEN GAS CONTAINING POTENTIALLY EXPLOSIVE QUANTITIES OF OXYGEN AND NOXIOUS PROPORTIONS OF RADIOACTIVE FISSION GASES; THE APPARATUS INCLUDING AN INTERNAL COMBUSTION ENGINE FOR CONVERTING SMALL INCREMENTS OF HYDROGEN TO WATER.

. WRIGHT March 13, M F OR CONTAMINATED HYDROGEN FROM DISPOSAL SYSTE ANUCLEAR REACTOR Original Filed Feb. 8, 1966 wzzm m5; @503 mm 20 $28M25355. oh 4 5C5 mozmfimm mmEEoE @W 3 mwwzmozoo I mm 7 55B 3 "5&3: I W49mommumlzonvl UU UQ.\ mm I 3 02.52 fi mm ow 3 S m I Q o. w a moZfiE v MII II mwwz oxm J w :5: m mwwz zuxw m Em.

N I L J K E lEDn. I

INVENTOR William E. Wright,

ATTO NEY WITNESSES United States Patent Ofitice Reissued Mar. 13, 19-73DISPOSAL SYSTEM FOR CONTAMINATED HYDROGEN FROM A NUCLEAR REACTOR WilliamE. Wright, Pittsburgh, Pa., assignor to Westinghouse ElectricCorporation, Pittsburgh, Pa. Original No. 3,362,883, dated Jan. 9, 1968,Ser. No.

525,909, Feb. 8, 1966. Application for reissue Sept. 21, 1969, Ser. No.869,970

Int. Cl. G21c 19/32 US. Cl. 176--37 4 Claims Matter enclosed in heavybrackets [I] appears in the original patent but forms no part of thisreissue specification; matter printed in italics indicates the additionsmade by reissue.

ABSTRACT OF THE DISCLOSURE An apparatus for disposing of contaminatedhydrogen gas containing potentially explosive quantities of oxygen andnoxious proportions of radioactive fission gases; the apparatusincluding an internal combustion engine for converting small incrementsof hydrogen to water.

Pressurized water cooled nuclear reactors include a water cooling systemfor transferring heat energy from the nuclear fuel to a steam generatingheat exchanger. Among other components, the cooling system includes asurge tank in which the changes in system water volume are accommodated.

The surge tank is a closed vessel normally containing water in the lowerportion and hydrogen in the upper portion.

Hydrogen, rather than some other gas, is used because hydrogen combineswith oxygen dissolved in the water and thus minimizes the oxygen contentof the water. Free oxygen in the water is undesirable because of itscorrosive effect on metal parts constituting the reactor as well as thewater cooling system.

Associated with the foregoing is the fact that radioactive fission gasessuch as krypton and xenon become dissolved in the water if a leakdevelops in any of the fuel tubes within the reactor. Such dissolvedgases are carried by the water to the surge tank where they escape intothe hydrogen gas atmosphere above the water. If the concentration ofsuch gases is allowed to become too great, the surge tank gas volumebecomes undesirably radioactive.

Thus, it is desirable to periodically purge and surge tank of thecontaminated hydrogen gas blanket. Also, whenever the cooling system isopened for maintenance or plant refueling, the hydrogen blanket must beremoved. In both of these cases an unusual waste producthydro gencontaminated with radioactive gasesrequires disposal.

Various means of oxidizing the hydrogen to eliminate the combustibilitydanger of the mixture have been employed, such as using a platinumcatalytic grid or a flame recombiner. Another method involves thedilution of the hydrogen with large quantities of an inert gas such asnitrogen. However, such methods have serious disadvantages. The methodof diluting with nitrogen requires the storage of large volumes of gasfor long periods of time. Both types of recombiners have consistentlypresented operating difficulties that primarily involve intermittentoperation.

:It has been found that the problem may be overcome by burning thecontaminated hydrogen in an internal combustion engine in which thehydrogen is mixed with measured amounts of oxygen and used as the enginefuel. Such a procedure is satisfactory because not only is it notsubject to the operating difficulties inherent in prior procedures, butit is relatively inexpensive and simple to use and it is inherentlyfail-safe.

Accordingly, it is a general object of this invention to providecontaminated hydrogen disposal system by burning hydrogen in smallbatches, i.e., a combustion chamber charge, thereby burning it in aninherently safe manner which is at the same time simply and easilyaccomplished.

It is another object of this invention to provide a contaminatedhydrogen disposal system which reduces large volumes of contaminatedhydrogen to water, plus chemically inert radioactive gases, and smallquantities of excess oxygen. The relatively small resultant volumes ofliquid and non-combustible gases can be processed routinely in theradioactive waste disposal systems that are a part of all nuclear powerplants.

Finally, it is an object of this invention to satisfy the foregoingobjects and desiderata in a simple and expedient manner.

The accompanying drawing is a schematic view of a nuclear reactor systemhaving a hydrogen batch burning system associated therewith inaccordance with the principles of the invention.

The present invention involves a system for eliminating hydrogen gaswhich has been contaminated with radioactive gaseous fission productsduring the operation of a nuclear reactor. In a water coolant system fora nuclear reactor a conduit is provided for circulating the coolant fromthe reactor and through a heat exchanger and back to the reactor. Thesystem also includes a surge tank in which excess water is stored formaintaining a relatively constant water volume in the system. The waterwithin the surge tank occupies the lower portion thereof and the upperportion is occupied by hydrogen gas which combines with any oxygen inthe water to prevent oxygen from corroding metal parts of the reactorcoolant system.

During operation of the system the hydrogen may gradually becomecontaminated with radioactive fission products and thus becomes anundesirable source of radition. As a result, it is desirable toeliminate the source by periodically burning off the hydrogen andreplacing it p with a new uncontaminated supply. For that purpose aninternal combustion engine is provided where the contaminated hydrogenis united with oxygen to form water. Other oxidizers such as air orhydrogen peroxide may be used. Subsequently, the water is separated fromthe non-combustible radioactive gases and the contaminated water andnon-combustible gases are separately disposed of, such as in sealedcontainers buried in the ground.

In the drawing a nuclear reactor 2 is provided with a water coolantsystem 4, which system includes a conduit 6, a heat exchanger 8, and acentrifugal pump 10. An associated system for accommodating changes inthe water volume, such as when the reactor heats up from a coldcondition, is provided and includes a conduit 12, a heat exchanger 14, aletdown valve 16, a reciprocating pump 18, and a surge tank 20. The heatexchanger 8 may be of conventional construction. The pump 10 operatesprimarily to maintain a constant flow of water around the closed circuitof the conduit 6 and through the reactor 2.

The surge tank 20 has the primary purposes of compensating for increasesand decreases in the water volume of the system such as when the watercircuit is heated up or cooled down. The lower portion of the tank 20 isoccupied by coolant water 24 and the upper portion is occupied primarilyby hydrogen gas, which is introduced through an inlet conduit 26. Aninterface 28 of water and hydrogen gas exists within the surge tank.

During operation of the reactor 10 the water frequently absorbscontaminants such as fission products and oxygen formed by hydrolysis.In order to prevent corrosion of the metal parts in the reactor coolantsystem, the oxygen must be eliminated from the water as completely aspossible.

The hydrogen gas serves that purpose. As the water 24 :irculates in andout of the surge tank, the hydrogen gas is absorbed at the interface 28and combines chemically with any oxygen dissolved in the water.

Over a period of time, however, the hydrogen gas may become contaminatedwith various fission products such as krypton and xenon gases which arehighly radioactive and, therefore, the gas volume becomes an undesirablev radioactivity source. As a result, the hydrogen gas is peri- Jdicallyreplaced. Also, when the reactor is shut down for maintenance or fuelreplacement purposes, the hydrogen blanket must be displaced.

Disposal of the hydrogen is accomplished by opening a valve 30 in aconduit 32 which leads to an internal combustion engine 34 where thehydrogen is mixed in a mixing device 36 with oxygen gas leading from asource 38 of oxygen through a conduit 40. The engine 34 is started by anelectric motor 42 and when combustion of the oxygen and hydrogen gasescommences, the electric motor is turned off and the engine isself-sustaining so long as there is sufficient hydrogen to maintaincombustion.

The engine 34 operates on an oxygen rich mixture so that the combustionprocess is as follows:

H +O +gaseous fission products H O+O +gaseous fission products-i-heatThe process is started by turning on the motor 42 and drawing thehydrogen and oxygen mixture into the combustion chambers of the engine34. When combustion stops for any reason, such as a malfunction orcompletion of the burning of the available hydrogen, the process stopsautomatically.

The combustion products include water in the form of steam and thenon-combustible radioactive gases which entered the hydrogen gas at thegas-water interface 28 within the tank 20. The combustion products leavethe burner 34 via the outlet 44, and are transmitted to a condenser 46where the steam is reduced to water. The water and non-combustibleradioactive gases then flow through an outlet 48 to a moisture separator50. Inasmuch as the water contains radioactivity, it is removed from themoislure separator 50 through an outlet 52 and is disposed of in aconventional manner for handling radioactive liquid waste products.

The non-combustible radioactive gases leave the moisture separator 50via an outlet 54 and are compressed in a gas compressor 56 from wherethey are transmitted to a gas holding tank 58 to decay to a saferadioactive level before being disposed of through a conduit 60 leadingto a stack (not shown).

Accordingly, the device and process of the present invention isinherently fail-safe. The volume of gas accumulating and requiringexpensive storage facilities is maintained at a minimum level. Thesystem involves a relatively inexpensive facility which has applicationin all plants that use a hydrogen blanket over a liquid which maycontain radioactive gases.

Finally, though the device of the present invention is disclosed asuseful in a nuclear reactor system, it is equally useful in the chemicalindustry where combustible gases to be disposed of are contaminated ornoxious.

Various modifications may be made within the spirit of the invention.

What is claimed is:

1. In a water coolant system for a nuclear reactor wherein a conduit isprovided for circulating water from a reactor and through a heatexchanger and to the reactor, and wherein a surge tank communicates withthe conduit for storing water containing contaminants in the lower tankportion and for containing hydrogen gas in the upper tank portion, thecombination with said tank of a gas fueled internal combustion enginemeans for burning the hydrogen gas with oxygen, said engine meansincluding a hydrogen-oxygen mixing device, conduit means between theupper tank portion and the engine means for conveying hydrogen gas tothe mixing device, and a supplemented source of oxygen attached to themixing device to supply oxygen in an amount in excess to react with thehydrogen to form water by combustion in the engine means.

2. The device of claim 1 in which the engine means includes means forseparating water resulting from the combustion of hydrogen and oxygenfrom non-combustible contaminants in the contaminated hydrogen gas.

3. The device of claim 1 in which the engine means includes an engineand means for starting the engine.

4. A system for disposing of hydrogen gas from a nuclear pressurizedwater system which includes a reactor, heat exchanger and a pump forcirculating water through the reactor in a closed circuit for coolingpurposes, and wherein the pressurized water system contains ivaryingquantities of hydrogen contaminated by radioactive fission gasesresulting from reactor operation, the improvement comp rising:

a conduit connected to the pressurized water systems for withdrawing thecontaminated hydrogen therefrom;

a separate source of oxygen not associated with the pressurized watersystem;

means connecting the separate oxygen source and contaminated hydrogenfrom the pressurized water system with a gas mixing device to form acombustible gas mixture;

an internal combustion engine coupled with the mixing device forreceiving and burning the hydrogen-oxygen mixture to form water, heatand contaminated non-combustible gases; and

separation means connected with the engine exhaust for separating thewater and contaminated non-combustible gases for later delivery toseparate storage facilities.

References Cited The following references, cited by the Examiner, are ofrecord in the patented file of this patent or the original patent.

UNITED STATES PATENTS 2,183,674 12/1939 Erren l2337 X 3,028,327 4/1962Weeks 176--37 3,041,134 6/1962 Weeks 17637 3,113,913 12/1963 Newton17637 3,166,478 1/1965 Lindstrom 176-37 FOREIGN PATENTS 221,254 8/1924Great Britain 12327 G OTHER REFERENCES I. W. Simpson: Proceedings ofInternational Conference on the Peaceful Uses of Atomic Energy, vol. 13,Power Reactors, pp. 211, 212, 220, 221, 222, 223.

REUBEN EPSTEIN, Primary Examiner

